By Kyösti Kontturi,Lasse Murtomäki,José A. Manzanares

Modelling of heterogeneous techniques, similar to electrochemical reactions, extraction or ion-exchange, frequently calls for fixing the shipping challenge linked to the method. because the methods on the section boundary are defined by way of scalar amounts and shipping amounts are vectors or tensors, coupling of them can happen in simple terms through conservation of mass, cost or momentum. during this booklet, delivery of ionic species is addressed in a flexible demeanour, emphasizing the mutual coupling of fluxes specifically. therapy is predicated at the formalism of irreversible thermodynamics, i.e. on linear (ionic) phenomenological equations, from which the main usually used Nernst-Planck equation is derived. barriers and assumptions made are completely discussed.

The Nernst-Planck equation is utilized to chose difficulties on the electrodes and in membranes. Mathematical derivations are provided intimately in order that the reader can study the technique of fixing delivery difficulties. every one bankruptcy encompasses a huge variety of workouts, a few of them extra hard than others.

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Ionic Transport Processes: In Electrochemistry and Membrane Science by Kyösti Kontturi,Lasse Murtomäki,José A. Manzanares


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